Spin switching in corrole radical complex
Spintronics is a cutting-edge field of developing new elec-tronic devices by manipulating the electron spin and magnetic mo-ment[1].Traditional spintronic research mainly focuses on transi-tion metals and inorganic semiconductors,while organic molecules have the advantage of being extremely easy to realize efficient spin control by modifying the specific external conditions for de-sired electronic structures and magnetic characteristics.Corrole,as a ring-contracted porphyrin,is the aromatic analog of the central macrocycle of vitamin B12.Corrole has a squeezed inner cavity and three inner NHs in its free-base form,making it easier to stabilize high-valent metal ions and thus a promising candidate in spintron-ics.
corrole、spin、complex、radical、switching
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O611.3;TP311;TN915.04
2024-02-03(万方平台首次上网日期,不代表论文的发表时间)
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