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10.1016/j.cclet.2023.108883

Spin switching in corrole radical complex

引用
Spintronics is a cutting-edge field of developing new elec-tronic devices by manipulating the electron spin and magnetic mo-ment[1].Traditional spintronic research mainly focuses on transi-tion metals and inorganic semiconductors,while organic molecules have the advantage of being extremely easy to realize efficient spin control by modifying the specific external conditions for de-sired electronic structures and magnetic characteristics.Corrole,as a ring-contracted porphyrin,is the aromatic analog of the central macrocycle of vitamin B12.Corrole has a squeezed inner cavity and three inner NHs in its free-base form,making it easier to stabilize high-valent metal ions and thus a promising candidate in spintron-ics.

corrole、spin、complex、radical、switching

35

O611.3;TP311;TN915.04

2024-02-03(万方平台首次上网日期,不代表论文的发表时间)

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中国化学快报(英文版)

1001-8417

11-2710/O6

35

2024,35(1)

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