Dendritic Macroinitiator for the Ring-Opening Polymerization of γ-Benzyl L-Glutamate N-Carboxyanhydride
By using OH-terminated polyarylether dendrimer and N-Fmoc-glycine as raw materials, the dendritic polyarylether 2-aminoacetate (G3-NH2) was synthesized via two step reactions. G3-NH2 as a macroinitiator for the ring-opening polymerization of γ-benzyl L-glutamate N-carboxyanhydride was investigated. It is found that the resulting copolymers possessed relatively high molecular weight and narrow molecular weight distribution (1.12< Mw/Mn<1.28).
Dendrimer、macroinitiator、ring-opening polymerization、polypeptide
13
2004-01-08(万方平台首次上网日期,不代表论文的发表时间)
共2页
420-421