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Microstructure and magnetic performance of Nd-Y-Ce-Fe-B sintered magnets after annealing

引用
Annealing has been widely recognized as a crucial approach to modify the microstructure and enhance the coercivity of Nd-Fe-B magnets.However,in the context of Nd-Y-Ce-Fe-B magnets with multiple rare earths(REs)exhibiting different diffusion behaviors,annealing effects on the magnetic properties become more compli-cated and remain unknown.In present work,through a comparative study between as-sintered and annealed Nd-Y-Ce-Fe-B magnet upon 50 wt%Y-Ce co-substitution of total REs,we found that annealing process surprisingly enhances the remanence from 1.17 to 1.20 T,with simultaneous coercivity increment from 612.9 to 660.7 kA·m-1,resulting in drastically improved maximum energy product from 242.0 to 263.5 kJ·m-3.Such a pecu-liar remanence enhancement is closely correlated to the preferential Y/Nd infiltration into RE2Fe14B main phase and Ce segregation into REFe2 intergranular phase,which consequently improve the intrinsic magnetism,as evalu-ated by Curie temperature(Tc),saturation magnetic polarization(Js)and magnetocrystalline anisotropy field(HA).Present work delights that different metallurgical behaviors of Nd/Y/Ce exert influential effects on the intrinsic and extrinsic magnetic properties and provide a novel approach toward high-performance 2:14:1-type per-manent magnets based on abundant RE mixtures.

after、annealing、magnetic、magnets、microstructure、performance、sintered

41

TP311;H319.3;D822.371.2

2022-05-11(万方平台首次上网日期,不代表论文的发表时间)

共6页

859-864

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稀有金属(英文版)

1001-0521

11-2112/TF

41

2022,41(3)

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国家重点研发计划“现代服务业共性关键技术研发及应用示范”重点专项“4.8专业内容知识聚合服务技术研发与创新服务示范”

国家重点研发计划资助 课题编号:2019YFB1406304
National Key R&D Program of China Grant No. 2019YFB1406304

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