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Nb2O5 nanoparticles embedding in graphite hybrid as a high-rate and long-cycle anode for lithium-ion batteries

引用
Lithium-ion batteries(LIBs)have exhibited extraordinary prospects due to their high energy and power density.However,the future development of LIB sis largely impeded by poor rate performance and cycling stability of the graphite anode.Here,we demonstrate a practical niobium pentoxide and graphite(Nb2O5/G)hybrid anode for high-performance LIBs via the scalable high-energy ball milling method.The as-prepared Nb2O5/G anode shows fast charging capability due to outstanding electrochemical kinetics from the surface pseudocapacitive insertion reaction of Nb2O5.Therefore,compared with pure graphite,the optimized 10%-Nb2O5/G hybrid anode(WNb2O5∶ Wgraphite=10∶90)exhibited high rate capacity of 270.0 mAh·g-1 at the current density of 2.0C(1.0C=372 mA.g-1)and high reversible capacity of 339.7 mAh·g-1 at 1.0C,together with better cyclic stability(340 cycles).This work provides an effective route toward LIBs with high rate and long cycle for a broad range of applications.

embedding、hybrid、anode、batteries、graphite、high-rate、lithium-ion、long-cycle、nanoparticles

41

TP391.1;TN911;R654.2

2022-05-11(万方平台首次上网日期,不代表论文的发表时间)

共8页

814-821

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稀有金属(英文版)

1001-0521

11-2112/TF

41

2022,41(3)

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国家重点研发计划“现代服务业共性关键技术研发及应用示范”重点专项“4.8专业内容知识聚合服务技术研发与创新服务示范”

国家重点研发计划资助 课题编号:2019YFB1406304
National Key R&D Program of China Grant No. 2019YFB1406304

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