分子印迹整体柱分离手性氨基酸衍生物的色谱研究

摘要：

@@ Since their introduction in 1992 by Fréchet and Svec[1], monolithic supports as stationary phases in high performance liquid chromatography (HPLC) and capillary electrochromatography (CEC) have gained significant interest due to a number of unique properties. Their ease of preparation, high reproducibility, versatile surface chemistry and fast mass transport are advantageous in a variety of applications[2-4]. Separations in diverse chromatographic modes have been performed in either HPLC or CEC, showing their strong point for high-speed separations of biological and synthetic molecules[5-12]. Although a number of papers have been reported on the application of monolithic supports as chiral stationary phases in CEC and pressure-assisted capillary electrochromatography (p-CEC)[13-19], few reports have so far been published on chiral monolithic stationary phases for liquid chromatography[20].

机标关键词：分子印迹、柱分离、手性氨基酸衍生物、色谱研究、Amino Acid、monolithic stationary phases、high performance liquid chromatography、chiral stationary phases、surface chemistry、mass transport

所属期刊栏目：22

分类号：O658(分析化学)

资助基金：国家自然科学基金20075032;国家重点基础研究发展计划973计划001CB510202;国家高技术研究发展计划863计划2001AA233031-4;the Knowledge Innovation program of Dalian Institute of Chemical Physics

在线出版日期：2004-09-09（万方平台首次上网日期，不代表论文的发表时间）

页数：共8页

页码：338-345