Corresponding author: ZHAO Suoqi. Tel: [phone]; E-mail: [e-mail].

摘要：

@@Direct catalytic oxidative conversion of light alkanes to alcohols using molecular oxygen as an oxidant is a challenging and important synthetical goal, which might be met by transition metal porphyrin complexes that are capable of forming active metal oxo intermediates via direct reaction with O2 in the presence of a co-reductant”1”. It was found that iron complexes of halogenated porphyrins were remarkably active catalysts for the hydroxylation of light alkanes by O2 without added co-reductants in an organic solvent such as benzene

关键词：supercritical state、propane、oxidation、isopropanol、homogeneous catalysis、porphyrin

所属期刊栏目：22

分类号：O643(物理化学（理论化学）、化学物理学)

资助基金：the Foundation of University of PetroleumZX9901;Selective Oxidation of Propane to Isopropanol in Supercritical PropaneHomogeneously Catalyzed by Iron Haloporphyrin

在线出版日期：2004-01-08（万方平台首次上网日期，不代表论文的发表时间）

页数：共2页

页码：411-412